Monday, November 26, 2012

"Form Follows Function"


The title of this post, a phrase often associated with architecture, is a concise way of saying that the appearance or aesthetics of a functional object often is constrained by its ultimate use. Synthetic sediment can be thought of in this way.  Its composition and to a lesser extent its appearance may be constrained by its specific application.  This might be a good working assumption for those developing synthetic sediment: decide a batch’s functionality and work backwards to develop a formulation to achieve that functionality. 

We think up many possible uses or functions for sediment in a laboratory setting: aquarium decoration, substrate for testing interactions between chemicals and sediment components, substrate for growing aquatic plants or culturing aquatic macro-invertebrates, a clean reference sediment to control test variables associated with physical properties of test sediment, a chemical-spiked positive control to confirm the observed response to a test sediment, and others.  Each of these uses, and others we might imagine, requires a different “minimum” level of detail or complexity of the sediment substrate; a substrate cannot be too complex for a given use, but complexity less than the minimum will not work.  We could think of natural sediment as having the highest level of complexity, so any sample of natural sediment will work for any use.  The accuracy of that statement might be debatable, but for our purposes the complexity of natural sediment is the benchmark to shoot for and to which synthetic substrate complexity is compared.

The first response might be to develop one, universally-complex synthetic substrate and use it for all possible functions and applications.  In practice, that might be an ambitious approach because of the difficulty in assuring that the complexity of the synthetic material matches the natural.  Secondly, replicating that level of complexity by multiple labs in multiple locations throughout the world would require a lot of time and expense by the participating labs.  For many applications, such effort would be over-kill.  Lastly, regional differences in natural sediment characteristics, or organism differences in micro-habitat requirements, would make a single universal synthetic substrate inappropriate.  This is one of the drawbacks with current synthetic sediment formulations.

So thinking of synthetic substrates as use-specific can simplify how specific labs might approach formulating it.  Recipes and components (type, number) would be specific to end-use, regional environment, data quality objectives and organism habitat needs.  To apply this approach requires a clear understanding of what components can or should be used for which end-use substrate.  This means knowing how each individual component affects and contributes to the characteristics of the whole, and how each interacts with the other components.

Most of my work with synthetic sediment so far is focused on researching, documenting and testing how individual components affect characteristics of the whole material.  This knowledge will help end-users of synthetic sediment select appropriate components and recipes for their specific needs.  Some components have little influence on substrate characteristics; large particle-size sand (silica; quartz) is an example.  Most have a strong affect on the characteristics of the whole material.  Examples include small particle-size geochemical clay (layered alumina-silicate minerals), geochemical silt (simple oxides, simple silicates, carbonates, feldspar and granite minerals), all types of organic matter, and mineral components like metal-sulfides.  One set of experiments, presented at a technical conference in Long Beach, California, demonstrated how the type and amount of mineral oxides included in a mixture can have a profound effect on pore water pH and on the cohesion and compaction properties of whole substrates.  You can find the summary of that presentation on page 313 of the 2012 conference abstract book, found online HERE

More tests will be done with other minerals and organic matter.  Stay tuned for more posts to this blog. 


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